Ketones and Aldehydes
Thursday, April 28, 2011 /5:47 PM
Ketones
- is a hydrogencarbon chain with a double bonded oxygen that is NOT on either end. IT IS USUALLY AROUND THE MIDDLE.
-follow standard rules and add -one to the parent chain
Examples:
Draw the structural diagrams for the following ketones.
1)2,4 dimethyl 3 pentanone
2) 5 bromo 2 chloro 3 ethyl 4 heptanone
Name the following ketones:
1) 4 methly 2 hexanone
2) 1 cyclopentanone
3) 5 bromo 4 phenyl 3 heptanone
Alydehydes
-is a compund that has a double bond oxygen at the END of a chain
- the simplest aldehyde is methanal AKA formaldehyde
- follow the standard rules and change the parent chain ending to "
-AL"
*
BE CAREFUL WHEN NAMING ALDEHYDES AND ALCOHOLS.*
Example:
Draw the following structural or line diagrams for
1) 3,3 dimethyl pentanal
2) Ethanal
3) 3 chloro 2 methyl hexanal
~christina :]
Functional Groups: Alcohol, Halides, Aldehydes, Ketones
/4:45 PM
- Organic compounds can contain elements other than C and H
- These are know as functional groups
- Carbon chains without functional groups are written as
- In Chemistry 11 we will learn about a different functional groups
- Alcohols
- Halides
- Aldehydes
- Ketones
- Carboxylic Acids
- Ethers
- Amines
- Amides
- Esters
Alcohols
- An alcohol is a hydrocarbon with a -OH bonded to it
- Same naming rule apply but the parent chain ending to -ol
ethanol
example:
- draw the structural diagrams for the following alcohols
- 3 methyl 6 propyl 1 octanol
Multiple -OH
- If a compound has more than one -OH group number both and add -diol, triol, ending.
1, 2 ethanediol
Halides
- Group 7 elements (F,Cl,Br,I) can bond to a hydrocarbon chain
- Naming follows standard rules with halides using floro-,chloro-, bromo- and iodo-
trichloromethane
-Chloe Ko
Alicyclics and Aromatics
Wednesday, April 20, 2011 /6:29 PM
-Carbon chains can form 2 types of closed loops
-Alicyclics are loops usually made with single bonds
-If the parent chain is a loop standard naming rules apply with one addition: "cyclo" is added infront of the parent chain
There are 3 different ways to draw organic compounds:
- Complete structural diagram
- Condensed structural diagram
- Line Diagram (mostly used because its way easier to draw and you dont have to include all the hydrogens) :)
*Numbering can start anywhere and go clockwise or counterclockwise on the loop but side chain numbers MUST be the lowest possible!*
Examples:
Name the following compounds:
1) 1,3 dimethyl [numbering is in red]
2) 1 methyl cyclopropane [numbering is in red]
Aromatics:
-Benzene (C6H6) is a cylic hydrocarbon with unique bonds between the carbon atoms
-Structurally it can be drawn with alternating double bonds
-careful analysis shows that all 6 c-c bonds are identical and really represent a 1.5 bond
-this is due to e- resonance
-e- are free to move all around the ring
Aromatic nomenclature:
-A Benzene molecule is given a special diagram to show its unique bond structure
-Benzene can be a parent chain or a side chain
-As a side chain is given the name phenyl
Examples:
Draw the diagrams for:
1) 1 methyl 2 butyl 3 ethyl benzene
2) 5 methyl 2 phenyl hexane
Name the following compunds:
1) 6 butyl 2,4 diethyl 1,3 dimethyl 5 propyl bezene
2) 6 ethyl 5 phenyl 2 propyl 1 nonene
~christina :]
Alkenes & Alkynes
Tuesday, April 19, 2011 /7:24 PM
Double & Triple Bonds
- carbon can form double and triple bonds with carbon atoms
- when multiple bonds form fewer hydrogens are attached to the carbon atom
- naming rules are almost the same as with Alkanes
- The position of the double/triple bonds always has the lowest number and is put in front of the parent chain
- Double bonds (Alkenes) end in -ene
- Triple bonds (Alkynes end in -yne
1 Butene
2 Butene
example
- What is the name of this akene?
- What is the name of this akene?
- What is the name of this Alkyne?
Trans & Cis Butene
- If two adjacent carbons are bonded by a double bond AND have side chains on them two possible compounds are possible
Multiple double bonds
- More than one double bond can exist in a molecule
- Use the same multipliers inside the parent chain
example
- draw the structural diagram.
Isoprene (2-methyl-1,3-butadiene)
Organic Compound: Nomeclature
Thursday, April 14, 2011 /5:38 PM
Organic Chemistry:
-O.C is the sutdy of Carbon compounds
-carbon forms multiple covalent bonds
-carbon compounds can form chains, rings or branches
-there are less than 100,000 non-organic compounds
-the organic compounds number more than 7,000,000
-the simplest organic compound are made up of hygrogen and carbon
eg. H H H
| | |
H-C-H = CH4 H- C -C-H =CH3CH3
| | |
H H H
-Saturated compounds have no double or triple bonds
-Compounds with only single bonds are called Alkanes and always end in -ane
-3 categories of Organic compounds
1) Straight chains
2) Cylic chains
3) Aromatics
STRAIGHT CHAINS (rules for naming):
1. Circle the longest continuous chain and name this as the
base chain
- meth, eth, prop...
2. Number the base chain so side chains have the lowest possible numbers
3. Name each side chain using the -yl ending
4. Give each side chain the appropriate number
- if there is more than one side chain, numbers / labels
are slightly different
5. List side chains alphabetically.
Name the folllowing compounds:
1) 2,2 diethyl 4 methyl pentane because the longest chain is 5 highlighted in red. The one's circled in dark blue are the side chains. The number that is written in there is the numbering system in the lowest as possible.
2) 2 methyl propane because the longest chain is 3. It doesn't mater how you number it because the side chain will always be two if you count one way and vise-versa.
Now it's time to draw the following compunds:
1) 2,3 dimethyl butane
2) 3 methly hexane [not all side chains chains will be in a straight line they can turn off into another direction]
3) 2,2,3 trimethylpentane
~christina chow :]
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Polar and Non-Polar Solvents
Sunday, April 3, 2011 /11:07 AM
Today our class had to determine if glycerin is either polar or non-polar. In our first observations we mixed water with table salt and sugar and they both dissolved in the water. When we mixed water with iodine is it did not dissolved. When we mixed paint thinner with table salt and sugar it did not disslove but when we mixed paint thinner and Iodine it dissolved. In our second observations we mixed water and glycerin and it was soluble. When we mixed paint thinner adn water is was not soluble. we concluded that when we mix two of the same substances [polar-polar OR non polar- non polar] it is not soluble, but when we mix two different substances [polar - non polar] it is soluble